Voltammogram Data Associated with Manuscript titled: "Strategies for Assessing the Limit of Detection in Voltammetric Methods: Comparison and Evaluation of Approaches."

Description

This data set contains the instrument files (.pssession) as well as the extracted voltammogram data as (.xlsx) for voltammetric analysis of lead, diphenylamine, ferrocyanide, naltrexone, and acetaminophen collected during the generation of calibration curves and serial dilutions. Ferrocyanide data was collected via cyclic voltammetry between -300 mV and +700 mV with a scan rate of 100 mV/s and a potential sweep of 2 mV. Lead and diphenylamine data was collected via square-wave anodic stripping voltammetry with a deposition potential of -950 mV for 120 s and then swept from -1000 mV to + 1200 mV with a potential step of 5 mV, amplitude of 25 mV, and frequency of 11 Hz. Naltrexone data was collected via square-wave voltammetry between -1000 mV and +1200 mV with a potential step of 15 mV, amplitude of 100 mV, and a frequency of 100 Hz. Acetaminophen data was collected via square-wave voltammetry for the anodic direction between -600 mV and +1000 mV and the cathodic direction from +1000 mV to -600 mV both with a potential step of 4 mV, amplitude of 250 mV, and a frequency of 75 Hz.

Resources

Name Format Description Link
0 Lead and Diphenylamine Data .pssession https://data.nist.gov/od/ds/mds2-3388/Lead%20and%20Diphenylamine%20Data.pssession
0 Acetaminophen Data .pssession https://data.nist.gov/od/ds/mds2-3388/Acetaminophen%20Data.pssession
0 Ferrocyanide Data .pssession https://data.nist.gov/od/ds/mds2-3388/Ferrocyanide%20Data.pssession
53 Lead and Diphenylamine Data .xlsx https://data.nist.gov/od/ds/mds2-3388/Lead%20and%20Diphenylamine%20Data.xlsx
53 Naltrexone Data .xlsx https://data.nist.gov/od/ds/mds2-3388/Naltrexone%20Data.xlsx
53 Acetaminophen Data .xlsx https://data.nist.gov/od/ds/mds2-3388/Acetaminophen%20Data.xlsx
53 Ferrocyanide Data .xlsx https://data.nist.gov/od/ds/mds2-3388/Ferrocyanide%20Data.xlsx
0 Naltrexone Data .pssession https://data.nist.gov/od/ds/mds2-3388/Naltrexone%20Data.pssession

Tags

  • limit-of-detection
  • electrochemistry
  • voltammetry
  • validation-parameters
  • forensic-science
  • forensic-chemistry
  • cyclic-voltammetry
  • square-wave
  • performance-measures

Topics

Categories