Real-time optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework
Description
[This repository contains the raw and source data for the manuscript "Real-time optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework".] Fully-aromatic, two-dimensional covalent organic frameworks (2D COFs) are hailed as candidates for electronic and optical devices, yet to-date few applications emerged that make genuine use of their rational, predictive design principles and permanent pore structure. Here, we present a 2D COF made up of chemoresistant β-amino enone bridges and Lewis-basic triazine moieties that exhibits a dramatic real-time response in the visible spectrum and an increase in bulk conductivity by two orders of magnitude to a chemical trigger - corrosive HCl vapours. The optical and electronic response is fully reversible using a chemical switch (NH3 vapours) or physical triggers (temperature or vacuum). These findings demonstrate a useful application of fully-aromatic 2D COFs as real-time responsive chemosensors and switches.
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http://data.europa.eu/88u/dataset/oai-zenodo-org-2634565 |
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http://data.europa.eu/88u/dataset/oai-zenodo-org-2634565 |
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http://data.europa.eu/88u/dataset/oai-zenodo-org-2634565 |
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http://data.europa.eu/88u/dataset/oai-zenodo-org-2634565 |
Tags
- covalent-organic-framework
- protonation
- gas-phase
- triazine
- band-gap-tuning