Molecular speciation of Ge within sphalerite, hemimorphite, and quartz from mine waste from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A.

Oxidation state and bonding environment of Ge in minerals within mine waste from sampled historical waste piles from the Tar Creek Superfund Site, Oklahoma, U.S. were determined by linear combination fits from x-ray absorption near edge spectroscopy (XANES) analysis. Ge content in quartz within these wastes was determined using XANES edge steps, and Ge content in sphalerite was compared using XANES edge steps versus electron microprobe analyses.
Data and methods reported are part of a research study published here:
White, S.J.O., Piatak, N.M., McAleer, R.J., Hayes. S.M., Seal, R.R. II, Schaider, L.A., Shine, J.P. Germanium redistribution during weathering of Zn mine wastes: implications for environmental mobility and recovery of a critical mineral, Applied Geochemistry, p. 105341, https://doi.org/10.1016/j.apgeochem.2022.105341.